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Topic: I2O5 molecolar geometry and ibridation  (Read 8090 times)

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Offline Excelinthewall

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I2O5 molecolar geometry and ibridation
« on: January 05, 2010, 12:15:44 PM »
I have a problem with iodine pentoxide  (I2O5): I know how the molecolar is , but i don't understand how the Iodine have a ibridation sp3 with a elettronical configuration 4d10 5s2 5p5 . Can someone help me? :) i hope it :)

happy new years everybody :) and good chemistry :P
(I'm sorry for my bad english :) )

Offline Schrödinger

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Re: I2O5 molecolar geometry and ibridation
« Reply #1 on: January 06, 2010, 12:59:05 AM »
Count the number of sigma bonds and number of lone pairs on each iodine atom, and see how all of them can be arranged with respect to each other.
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Offline AWK

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Re: I2O5 molecolar geometry and ibridation
« Reply #2 on: January 06, 2010, 02:13:39 AM »
I have a problem with iodine pentoxide  (I2O5): I know how the molecolar is , but i don't understand how the Iodine have a ibridation sp3 with a elettronical configuration 4d10 5s2 5p5 . Can someone help me? :) i hope it :)

happy new years everybody :) and good chemistry :P
(I'm sorry for my bad english :) )
In my opinion you are quite right. Geometry of iodine pentoxide is far from tetrahedral arrangement of orbitals but often (incorrectly) chemists use sp3 as synonym of tetrahedral

see paper on its crystal structure:
http://actachemscand.org/doi/10.3891/acta.chem.scand.24-1912
AWK

Offline aieeee

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Re: I2O5 molecolar geometry and ibridation
« Reply #3 on: January 13, 2010, 01:27:47 AM »
here's a trick for it.
we know , I2O5 is an anhydride of iodic acid (HIO3). thus , hybridisation of I will be same in iodic acid as that of the anhydride i.e. sp3.

Offline Excelinthewall

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Re: I2O5 molecolar geometry and ibridation
« Reply #4 on: January 15, 2010, 12:04:00 PM »
so, thank you very much  :) I resolve my problem :P .

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