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Topic: Cure for acid rain  (Read 8340 times)

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Offline jsmith613

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Cure for acid rain
« on: March 09, 2010, 05:06:27 PM »
My teacher spoke about Lime (Calcium Hydroxide) being the cure for acid rain. He said that one has to filter the gasses before they leave the factory through Ca(OH)2 in order to prevent acid rain. And btw, the product HAS to be CaSO4

Here is my question: Are the filtered substances pure gasses or actual H2SO4 etc..

THis is what i was thinking:

I thought: SO3 + Ca(OH)2 --> CaSO4 + H2O - this may be wrong
BUT
SO2 + O2 + H2O --> H2SO4
H2SO4 + Ca(OH)2 --> CaSO4 + H2O

which equation works better for this circumstance

Offline skyjumper

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Re: Cure for acid rain
« Reply #1 on: March 09, 2010, 10:07:59 PM »
Which one is the largest cause of acid rain? That's what the teachers probably looking for.

Offline vhpk

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Re: Cure for acid rain
« Reply #2 on: March 10, 2010, 02:28:31 AM »
My teacher spoke about Lime (Calcium Hydroxide) being the cure for acid rain. He said that one has to filter the gasses before they leave the factory through Ca(OH)2 in order to prevent acid rain. And btw, the product HAS to be CaSO4

Here is my question: Are the filtered substances pure gasses or actual H2SO4 etc..

THis is what i was thinking:

I thought: SO3 + Ca(OH)2 --> CaSO4 + H2O - this may be wrong
BUT
SO2 + O2 + H2O --> H2SO4
H2SO4 + Ca(OH)2 --> CaSO4 + H2O

which equation works better for this circumstance
Okay, you've determined the main cause for the acid rain, that's SO2 and H2SO4. The first reaction is wrong since to convert SO2 to SO3 isn't easy. The second series, it isn't correct since H2SO4 isn't a volatile substance, so it's difficult to vaporize in order to cause acid rain, for the acid rain, the oxidation occurs in the atmosphere and here you use Ca(OH)2 to avoid the agent that causes acid rain. So can you rewrite the equation?
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Offline jsmith613

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Re: Cure for acid rain
« Reply #3 on: March 10, 2010, 06:02:34 AM »
Quote
So can you rewrite the equation?

Ca(OH)2 + SO2 + O2 --> ???

Offline vhpk

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Re: Cure for acid rain
« Reply #4 on: March 10, 2010, 07:29:56 AM »
Quote
So can you rewrite the equation?

Ca(OH)2 + SO2 + O2 --> ???
Why do you insist on oxygen? It's required for the oxidation but what you need now is only to remove sulfur dioxide .
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Offline jsmith613

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Re: Cure for acid rain
« Reply #5 on: March 10, 2010, 02:04:54 PM »
Why do you insist on oxygen? It's required for the oxidation but what you need now is only to remove sulfur dioxide .

SO2 + O2 --> SO3 (this process DOES take place industrially - e.g: contact process)

Ca(OH)2 + SO3 --> CaSO4 + H2O?

Offline skyjumper

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Re: Cure for acid rain
« Reply #6 on: March 10, 2010, 02:48:48 PM »
Per wikipedia:In the gaseous form, this species is a significant pollutant, being the primary agent in acid rain

So, the SO3 equation works, because SO3 is a main component of acid rain.

Offline jsmith613

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Re: Cure for acid rain
« Reply #7 on: March 10, 2010, 02:52:40 PM »
So, the SO3 equation works, because SO3 is a main component of acid rain.

Thanks for clarifying!

Offline vhpk

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Re: Cure for acid rain
« Reply #8 on: March 11, 2010, 07:56:48 AM »
Why do you insist on oxygen? It's required for the oxidation but what you need now is only to remove sulfur dioxide .

SO2 + O2 --> SO3 (this process DOES take place industrially - e.g: contact process)

Ca(OH)2 + SO3 --> CaSO4 + H2O?
Correct, but in industry, people don't release SO3 outside since it's very toxic, most of the SO3 is used for making sulfuric acid, and the amount of releasing is very small, the byproduct of industry usually SO2 and so the equation must be the reaction between Ca(OH)2 and SO2.
@skyjumper: wikipedia is correct but SO2 is the precursor of SO3, and the gas in industrial exhausted gas that you found is SO2 not SO3.
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