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What is the total volume of your solutions? How much KI do you have initially?
At a simple level, yes, the volume is additive.So how are the concentration and volume related, for a given amount of substance?
OK, If you have 1.00 mol dm-3, how many moles in 5.0 cm-3?
No, not 5 mol. How many cm3 in 1 dm3 ?
OK, so if there are 1000 cm3 in 1 dm3, and you have 0.1 mol in 1 dm3, how many moles in 1000 cm3? In 5 cm3?