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Topic: Average equilibrium constant?  (Read 11715 times)

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Offline IDudeScience

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Average equilibrium constant?
« on: March 22, 2010, 07:54:24 PM »
How does one calculate the average equilibrium constant? I have 4 values; 13, 24, 36, and 49. Do I add them all up and divide it by 4 to get the average? Thanks

Offline renge ishyo

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Re: Average equilibrium constant?
« Reply #1 on: March 23, 2010, 05:44:47 PM »
I believe so.

Offline cliverlong

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Re: Average equilibrium constant?
« Reply #2 on: March 23, 2010, 07:11:53 PM »
How does one calculate the average equilibrium constant? I have 4 values; 13, 24, 36, and 49. Do I add them all up and divide it by 4 to get the average? Thanks
My instinct asks me to question how can you calculate a meaningful average that is supposed to represent an equilibrium constant when the values you have calculated vary by over 3-fold or over 300% ? Can you repeat any of the experiments to check values? Are you calculating the equilibrium constant using a valid equation? Where do you get your equation for Kc from?

For example if the equation is supposed to be

Kc = [A]/[C]

and you are calculating

Kc = [A]2/[C]

you will get inconsistent answers as you vary concentration of reactant

The following article http://en.wikipedia.org/wiki/Equilibrium_constant uses a different version of the equation to calculate the Kc including wonderful terms such as "activity" and "fugacity"

Clive

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