November 25, 2024, 10:53:25 AM
Forum Rules: Read This Before Posting


Topic: Pericyclic reactions  (Read 2564 times)

0 Members and 1 Guest are viewing this topic.

Offline chiddler

  • Regular Member
  • ***
  • Posts: 36
  • Mole Snacks: +2/-0
Pericyclic reactions
« on: June 03, 2010, 02:49:29 AM »
Hello fellow chemists and, like myself, chemist wannabes. I would really like assistance understanding pericyclic reactions.

My professor told us a rhyme..."when heat is on, 4e is con". I do not understand how to apply con/disrotary rotations to a reaction. Fodder to exemplify this can be one of my homework questions:

How should the orbitals be drawn in HOMO and LUMO? I would really appreciate an answer to this first along with any information you have patience enough to include that may help me.

Thanks very much!

Offline Dan

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 4716
  • Mole Snacks: +469/-72
  • Gender: Male
  • Organic Chemist
    • My research
Re: Pericyclic reactions
« Reply #1 on: June 03, 2010, 07:23:42 AM »
I highly recommend you get these out of the library:

Frontier orbitals and organic chemical reactions - Ian Fleming
Pericyclic reactions (Oxford chemistry primer) - Ian Fleming
My research: Google Scholar and Researchgate

Offline chiddler

  • Regular Member
  • ***
  • Posts: 36
  • Mole Snacks: +2/-0
Re: Pericyclic reactions
« Reply #2 on: June 03, 2010, 01:20:09 PM »
Thanks I found it in the catalog; I will take a look at it.

Sponsored Links