I am having problem with this question where the same reaction mixture leads to different products under diff conditions.
I have no clues about reaction 1
For reaction 2: I guess the the reaction follows an azo-coupling route...?
http://en.wikipedia.org/wiki/Azo_couplingFor reaction 3: I think the strongly acidic medium converts the -NH
2 into -NH
3+, which being a meta-directing group, leads to Ph
+ addition via EAS at the meta position.
Correct me if I am wrong, and please suggest some mechanism for the 1st reaction.