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Topic: Balance redox equation  (Read 2498 times)

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Offline huskywolf

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Balance redox equation
« on: October 20, 2010, 03:59:10 PM »
Hi,

Can you tell me if I balanced this equation correctly please?

MnO4- + Fe2+ + H+ => Fe3+ + Mn2+ + H2O
=
MnO4- + Fe2+ + 8H+ => Fe3+ + Mn2+ + 4H2O
Fe is oxidised, and Mn is reduced
? Thanks

Offline sinthreck

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Re: Balance redox equation
« Reply #1 on: October 20, 2010, 04:19:14 PM »
Charge is not balanced.

LHS: -1+2+8 = +9
RHS: 3+2 = +5

I just had a go at this questions and came up with this result:

Mn04- + 5Fe2+ + 8H+  :rarrow: Mn2+ + 5Fe3+ + 4H2O

The charge is balanced (+17 on each side).

The only thing is, when I balanced it, I ignored the original H+ and H2O that was in the equation. I'm not sure you can do this.

Offline sinthreck

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Re: Balance redox equation
« Reply #2 on: October 20, 2010, 04:26:48 PM »
Taken from my textbook:

Balancing redox reactions in aqueous solutions:

Step 1) Identify and separate half-reactions
Step 2) For each half-reaction
           - Balance elements (except H and O)
           - Balance O using H2O
           - Balance H using H+
           - Balance charge using electrons.
Step 3) Equalise number of electrons in each half-reaction (i.e. multiply half reaction by a factor)
Step 4) Add half-reactions (cancel identical species)
Step 5) Check elements and charges balance


On second thoughts, I didn't really ignore the H2O and H+ in the original reaction. My answer should be fine.

Offline huskywolf

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Re: Balance redox equation
« Reply #3 on: October 20, 2010, 04:30:28 PM »
Great ,thanks for the help people  :)

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