K
2SO
4 + BaCl
2 BaSO
4 + 2KCl
Since you need to determine if the volume of BaCl
2 added is enough for precipitation of sulphate, you should calculate the number of moles of K
2SO
4 present and BaCl
2 added, then compare the two. If number of moles of BaCl
2 >= those of K
2SO
4, then the BaCl
2 is sufficient to carry out the reaction.
According to my calculations, no. of moles of K
2SO
4 = 0.002998
And no. of moles of BaCl
2 is coming ouit to be 0.004524, which is definitely greater than the value mentioned above. So BaCl
2 is sufficient to carry out the above precipitation reaction (i.e., sulphate has been completely precipitated)