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Topic: Acid catalyzed dehydration of alcohols  (Read 2458 times)

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Offline Bob Sacamano

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Acid catalyzed dehydration of alcohols
« on: January 20, 2011, 12:08:38 AM »
I've been learning about the acid catalyzed dehydration of alcohols and I was wondering if instead of using a strong acid to dehydrate the alcohol you could use a strong base such as NH2- to pull a hydrogen off a carbon adjacent to the hydroxyl group (as in the case of removing a Br- ion to form a double bond). Would this work?

Offline rabolisk

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Re: Acid catalyzed dehydration of alcohols
« Reply #1 on: January 20, 2011, 12:34:18 AM »
I think this belongs in the organic chemistry forum. Nevertheless, base catalysis doesn't work because OH- is not a good enough leaving group. Acid catalysis converts it to a good leaving group, which is key to dehydration.

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