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Topic: Exam question I got wrong  (Read 3453 times)

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Offline Bjc51192

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Exam question I got wrong
« on: February 20, 2011, 07:36:06 PM »
Hello, I got this question wrong on an exam. can you guys explain to me step by step  how to solve it?

A sample conaining both HCl and HNO3 had a density of 1.083g/ml. A 41.00 ml amount of this sample required 34.72 ml of 0.2489 M NaOH for titration. Another 41.00 ml amount of this sample required 22.51 ml of 0.1866 M AgNO3 for titration. Calculate the mass percent of HNO3 (molar mass = 63.018 g/mol) in the sample.

Offline opti384

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Re: Exam question I got wrong
« Reply #1 on: February 20, 2011, 08:26:20 PM »
First determine the mass of the mixture of HCl and HNO3. Then think about what do the titrations with NaOH and AgNO3 mean.

Offline Bjc51192

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Re: Exam question I got wrong
« Reply #2 on: February 20, 2011, 09:02:33 PM »
First determine the mass of the mixture of HCl and HNO3. Then think about what do the titrations with NaOH and AgNO3 mean.

can you work it out? I want to see how its done number wise

Offline opti384

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Re: Exam question I got wrong
« Reply #3 on: February 20, 2011, 09:27:26 PM »
You have the density and the volume is given. From here you can determine the mass.

For the first titration, H+ will be neutralized with OH- from the base NaOH.

For the second titration, Cl- from HCl will form a precipitate with Ag+, thus forming AgCl.

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