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Topic: What is the structure of the hydrochloride salt of an amine?  (Read 5841 times)

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Offline nfredin

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What is the structure of the hydrochloride salt of an amine?
« on: March 02, 2011, 12:28:50 PM »
Is the actual structure of an amine hydrochloride salt just the aminium ion with a chloride counterion (H covalently bound to N and N+ ionically associated with Cl-, as opposed to H covalently bound to Cl)?  If so, why is it so seldom represented that way (e.g., triethylammonium chloride rather than triethylamine HCl)?

Offline voidSetup

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Re: What is the structure of the hydrochloride salt of an amine?
« Reply #1 on: March 02, 2011, 03:06:19 PM »
Yes it is an ammonium ion with a chloride counterion.  The H protonates the nitrogen of the amine, and the positive charge lies on the nitrogen.  Since it is a salt is has an ionic bond (the N-Cl bond). I think sometimes people would call it something like triethylamine HCl to show that it was crystalized using HCl.  You could use something else as the counterion.

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