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Topic: how to Increase conjugation of a molecule  (Read 3930 times)

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Offline ks1

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how to Increase conjugation of a molecule
« on: April 07, 2011, 08:40:21 PM »
I was wondering how would you increase conjugation of Dibenzalacetone to increase it's UV characteristics thereby increasing its Sunscreen role


Offline Honclbrif

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Re: how to Increase conjugation of a molecule
« Reply #1 on: April 07, 2011, 09:43:30 PM »
Increasing conjugation is as simple as adding more alternating single and double bonds.

However, remember your particle in a box: increasing conjugation redshifts absorption. If it gets too long it will begin absorbing in the visual range, which wouldn't make a very good sunscreen, would it?

What other physical parameter would it be advantageous to modify to make a better sunscreen? Hint: think Beer's Law...
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Offline ks1

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Re: how to Increase conjugation of a molecule
« Reply #2 on: April 07, 2011, 09:59:02 PM »
molar absorptivity???

Offline Honclbrif

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Re: how to Increase conjugation of a molecule
« Reply #3 on: April 07, 2011, 10:03:07 PM »
If you were using a sunscreen, would you want one with a longer absorption wavelength, or a higher molar absorptivity?
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Offline ks1

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Re: how to Increase conjugation of a molecule
« Reply #4 on: April 07, 2011, 10:06:02 PM »
The increase in conjugation makes it easier for electrons to jump to a higher energy level hence longer wavelength of light to be absorbed and transmitted

Thanks

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