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Topic: A quick Enthalpy question: Modified  (Read 1723 times)

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Offline KyleH

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A quick Enthalpy question: Modified
« on: April 20, 2011, 09:57:09 PM »
Alright so I have to finish up an Enthalpy reaction.  We did experiments in class and constructed chemical equations.  The question is: find the heat of combustion of Magnesium.

So all I need to know to actually finish that question is what it actually means.... :P
I'm trying to set up an equation that shows the beginning of the reaction and the end.

What i have is Mg + O2g = MgO[/s][/s]

Okay, and here are my other equations

MgCl2 + H2O ---> MgO + 2HCl        H = 0.4184 kJ
2HCl + Mg     ------------> H2 + MgCl2 H =-1.338 kJ
H2[/sub] + 1/2O2 -------> H2O         H = -285.8 kJ


My experimental heat of combustion per mol is -286.720
This is horribly wrong, with a percent error of more than 50%.  The real enthalpy value is -601.6 kJ

Does anyone see what I could've done wrong?  I used Hess's law, which states the steps of individual reactions adds up to the total reaction.  Maybe my equatoins aren't balanced and i don't realize it?
« Last Edit: April 20, 2011, 10:48:26 PM by KyleH »

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