Chemical Forums
1 Hour
1 Day
1 Week
1 Month
Forever
December 12, 2024, 01:53:40 PM
Forum Rules
: Read This Before Posting
Home
Help
Search
Login
Register
Chemical Forums
Chemistry Forums for Students
Organic Chemistry Forum
Alkylation/Michael HW Help
« previous
next »
Print
Pages: [
1
]
Go Down
Topic: Alkylation/Michael HW Help (Read 2381 times)
0 Members and 2 Guests are viewing this topic.
Arait
Regular Member
Posts: 17
Mole Snacks: +0/-0
Alkylation/Michael HW Help
«
on:
April 24, 2011, 05:24:16 PM »
Hi, I had a few homework problems that are driving me nuts, and I'm down to my last attempt with all of them. As a last resort, I thought I would ask for help on here. The first problem is a reaction I just can't get right, and for the second and third problems you are supposed to show the starting materials (#2 is the starting materials for an alkylation and #3 is starting materials for a Micheal reaction).
The fourth picture is the reaction that leads to the product in the final pic. That pic is correct structurally, but it tells me that I need to indicate the stereochemistry at each stereocenter (lowest energy conformation). So all I really need help with on the last one is the configuration at each center.
You can click on each pic to see it bigger.
Logged
plankk
Full Member
Posts: 150
Mole Snacks: +20/-4
Gender:
Re: Alkylation/Michael HW Help
«
Reply #1 on:
April 25, 2011, 02:31:34 AM »
The first task is connected with making an enolate. The alfa protons will be exchanged for deuteriums.
In the third example try to find 1,5-diCO relationship.
For the second and fourth picture I also have an idea but I'm not so sure about it. Let somebody better express his opinion.
Logged
Print
Pages: [
1
]
Go Up
« previous
next »
Sponsored Links
Chemical Forums
Chemistry Forums for Students
Organic Chemistry Forum
Alkylation/Michael HW Help