You don't really need initial concentrations. Just use algebra.
For example:
25% glucose to decompose
ln (Ao/A) = kt
A is the concentration after time t
so, for 25% to decompose, this means that 75% of Ao will be left.
Therefore, A = 0.75 Ao. The Ao term would be cancelled out. The final equation would look like:
ln (1/0.75) = kt
You know k, find t.