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Topic: Plz help me with this issue  (Read 2053 times)

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Offline ignatius111

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Plz help me with this issue
« on: September 16, 2011, 09:02:48 AM »
Hello, I´m working in a biologic lab and i got a question about chemistry reaction:

Well i need to know if it is a REDOX reaction and in this case what is the electronical balance:

I got 2,3,5- trihydroxybenzoate for descarboxilation to: 1,2,4- trihydroxybenzene + CO2

thanks so much

Offline orgopete

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Re: Plz help me with this issue
« Reply #1 on: September 18, 2011, 01:23:16 PM »
Although this could appear to be so, I think it is not. The carboxylate carbon, after reaction is carbon dioxide. The benzene ring goes from a carbon-carbon bond to a carbon-hydrogen bond. If we were to add water to carbon dioxide, then we might draw an analogy to an hydrolysis reaction. If an ester were hydrolyzed, a C-OR bond is hydrolyzed with water and the C-OR bond is replaced with C-OH on carbon and HOR on oxygen.

In this example if water were added, the C-CO2H bond is replaced with C-H and HOCO2H ( :rarrow: H2O + CO2).

The reaction does not involve water. I simply used it as an analogy to an hydrolysis reaction. Since hydrolysis is not a redox reaction, I was drawing an analogy of this reaction to an hydrolysis reaction by introducing a phantom water. Carbon dioxide is the product.
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