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Topic: Ionic bond strength  (Read 3823 times)

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Offline Qwertyqwerty

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Ionic bond strength
« on: October 04, 2011, 02:27:10 AM »
What are the factors that determine the strength of an Ionic bond?
Taking the example of LiF and K20, why does LiF have a stronger bond strength?

Offline PaintYourFuture

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Re: Ionic bond strength
« Reply #1 on: October 06, 2011, 04:34:02 AM »
Electronegativity

Offline jp92celtic

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Re: Ionic bond strength
« Reply #2 on: October 06, 2011, 11:26:07 AM »
look at a table of electronegativity values and calculate the difference between your two atoms

Offline Qwertyqwerty

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Re: Ionic bond strength
« Reply #3 on: October 07, 2011, 07:31:27 AM »
Isn't there a way to find it out without looking at the electronegativity table? Some general rules one might follow?

The question I had was :
Arrange the bonds in order of the increasing ionic character of the molecules :
LiF, K2O, SO2, N2 and ClF3

Of which the answer was
N2<SO2<ClF3<LiF<K2O

I can't understand as to why K2O has a stronger ionic character than LiF.

Offline jp92celtic

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Re: Ionic bond strength
« Reply #4 on: October 07, 2011, 05:55:50 PM »
as a general rule, looking at the periodic table can help:
N2 obviously has equal EN values, and shares perfectly equally (covalent)
SO2 has S and O which are both in the same column, one above the other, so they are relatively close in EN.
ClF3 has the same situation as above but are to the right (more EN)
LiF are hugely separated left to right, but are in the same row as each other.
K2O is also separated a lot left to right, but K is two whole rows below O, so therefore it has the greatest difference in EN.

Offline Qwertyqwerty

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Re: Ionic bond strength
« Reply #5 on: October 08, 2011, 02:09:18 AM »
Finally understood. Thank you  :)

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