Definitely urea, seeing as it laid the foundation for organic chemistry.
So let's see, so far we have classics (benzene, urea), organometallic reagents (Grignard, Grubbs). I still think it'd be a good idea to have a molecule that symbolizes the organic chemistry of life. Even a DNA base would suffice, say adenine, which is pretty simple structurally.
Perhaps should also throw in palladium tetrakis, since palladium chemistry has become indispensable these days.