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Topic: Copper Solubility in Water with pH 5  (Read 3878 times)

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Offline Math99

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Copper Solubility in Water with pH 5
« on: December 29, 2011, 09:35:05 AM »

Hello,

I have a problem with this task:

"Water with pH 5 and reduction potential +0.30 V flows through copper pipe at 25 °C. Calculate how much copper dissolves (in ppm) in water due to corrosion of this pipe. Standard reduction potential of copper Cu0/Cu2+ is 0.34 V."

I spent lot of hours with lot of calculations without any glory :( Please, is there anybody who could try to help me?

This figure could be helpful:

http://www.advancedaquarist.com/2003/5/chemistry_album/figure3.gif

I tried to use Nernst equation:

Eh = E0 - (RT / nF)*(lnQ).

The main equation I used was:

Cu + 2H+ -> Cu2+ + H2.

Without any glory :(

Offline Vidya

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Re: Copper Solubility in Water with pH 5
« Reply #1 on: January 02, 2012, 10:12:10 AM »
Now lnQ =ln [CU2+]/[H+]^2
now you know that pH =5
[H+]= 10^-pH=10^-5
Ecell =0.30V
E0 cell= 0.34V
Plug in the values in the Nernst equation and you will get [CU2+]

Offline Math99

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Re: Copper Solubility in Water with pH 5
« Reply #2 on: January 02, 2012, 11:25:14 AM »
I do not think so  :( ...

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