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Dear members,I would like to know how to convert aliphatic terminal alkyl chain to azide (N3).Thanks in advanceSimonraj
Quote from: simonraj on April 06, 2012, 02:03:58 AMDear members,I would like to know how to convert aliphatic terminal alkyl chain to azide (N3).Thanks in advanceSimonrajHave you any ideas?(i) bromination/chlorination (ii) Aq. Sodium azide -----> Alkyl azide
Quote from: discodermolide on April 06, 2012, 02:19:08 AMQuote from: simonraj on April 06, 2012, 02:03:58 AMDear members,I would like to know how to convert aliphatic terminal alkyl chain to azide (N3).Thanks in advanceSimonrajHave you any ideas?(i) bromination/chlorination (ii) Aq. Sodium azide -----> Alkyl azide
Quote from: simonraj on April 06, 2012, 02:48:38 AMQuote from: discodermolide on April 06, 2012, 02:19:08 AMQuote from: simonraj on April 06, 2012, 02:03:58 AMDear members,I would like to know how to convert aliphatic terminal alkyl chain to azide (N3).Thanks in advanceSimonrajHave you any ideas?(i) bromination/chlorination (ii) Aq. Sodium azide -----> Alkyl azideThat would give you some product along with a host of others because halogenation does not just occur at the chain terminus.
Ok, how to convert dodecane to 1-dodecanamine?
Plese tell meIs this possible ? R-(CH2)n-CH3 Chlorine, TEL and Temp: 1400C------> R-(CH2)n-CH2-Cl
Quote from: simonraj on April 06, 2012, 05:19:12 AMPlese tell meIs this possible ? R-(CH2)n-CH3 Chlorine, TEL and Temp: 1400C------> R-(CH2)n-CH2-ClWhat is TEL?As I said you will get terminal chlorination but it will be a MINOR product.