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Topic: Halogen reactivity issue  (Read 1869 times)

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Offline Rutherford

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Halogen reactivity issue
« on: September 21, 2012, 11:40:01 AM »
The reaction: 2KI+Cl2 :rarrow: 2KCl+I2 is possible because chlorine is more reactive than iodine.
The reaction that bothers me is:
I2+2KClO3 :rarrow: 2KIO3+Cl2
How is it possible?

Offline Dan

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Re: Halogen reactivity issue
« Reply #1 on: September 21, 2012, 12:20:09 PM »
Both proceed for the same reason:

R1 + Ox1  ::equil:: R2 + Ox2

Here, R is the reductant, Ox is the oxidant.

If Ox1 is a stronger oxidant than Ox2, then the equilibrium lies to the right.

Q: For the second equation, can you identify which reagents are the reductants and which are the oxidants?
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Offline Rutherford

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Re: Halogen reactivity issue
« Reply #2 on: September 21, 2012, 12:41:45 PM »
If I understood what you wanted to say: From the 1st reaction I see that Cl2 is a stronger oxidant than I2, that means that it is also a weaker reductant than I2. In the second equation I2 and Cl2 are the reductants, but as I2 is stronger the equilibrium shifts to the right. Good?

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