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Topic: Resonance structure of ClO3-  (Read 5479 times)

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Offline Dazedandconfused

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Resonance structure of ClO3-
« on: November 12, 2012, 02:57:07 PM »
I'm supposed to draw all of the resonance structures of the ClO3- ion. The ones I drew, I put a single bond between each O and the Cl, gave two of the O 3 lone pairs and one O 2 lone pairs, and the Cl 2 lone pairs. It makes sense to me, because if you subtract the 26 total valence electrons from the 32 total noble gas configuration electrons, you get 6 bonding electrons, which makes 3 single bonds. That gives me a trigonal bipyramidal shape. However, why is it that everywhere I look on the internet, Cl only has one lone pair, and at least one bond is a double?

Thanks!

Offline Dan

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Re: Resonance structure of ClO3-
« Reply #1 on: November 12, 2012, 05:22:09 PM »
and one O 2 lone pairs

The O with 2 lone pairs and a single bond (as you describe) only has 6 electrons in its outer shell. Perhaps this will help you correct your structure...

Also, you may find this helpful: http://www.youtube.com/watch?v=Bx5_ae6mA-A
My research: Google Scholar and Researchgate

Offline Dazedandconfused

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Re: Resonance structure of ClO3-
« Reply #2 on: November 12, 2012, 06:14:13 PM »
Ahh, I get it. The way I did it forms a much less stable molecule. Thanks a lot for your assistance!

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