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Topic: Coffee Cup Calorimetry?  (Read 6738 times)

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Offline mudkip26

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Coffee Cup Calorimetry?
« on: November 24, 2012, 10:50:55 AM »

In a coffee-cup calorimeter, 1 mol NaOH and 1 mol HBr initially at 23.5 oC (Celsius) are mixed in 100g of water to yield the following reaction:
NaOH + HBr → Na+(aq) + Br-(aq) + H2O(l)

After mixing the temperature rises to 84 oC. Calculate the change in enthalpy of this reaction.

Specific heat of the solution = 4.184 J/(g oC)

State your answer in kJ with 3 significant figures. Don't forget to enter the unit behind the numerical answer.

The molecular weight of NaOH is 40.0 g/mol, and the molecular weight of HBr is 80.9 g/mol.
ΔH = ?

I keep doing it as such

ΔH=-(c)(m)(ΔT)

So,

ΔH=-(4.184)(100+80.9+40.0)(84-23.5)

Where am I going wrong?

Offline Borek

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Re: Coffee Cup Calorimetry?
« Reply #1 on: November 24, 2012, 12:08:22 PM »
Why do you think you are doing it wrong?

And what is the result that you got?
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Offline mudkip26

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Re: Coffee Cup Calorimetry?
« Reply #2 on: November 24, 2012, 12:37:03 PM »
Why do you think you are doing it wrong?

And what is the result that you got?
I don't know where I'm going wrong.

The answer I keep getting is 54992.6132
And then divided by 101.3 is 542.8 or 543

Offline Borek

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Re: Coffee Cup Calorimetry?
« Reply #3 on: November 24, 2012, 01:35:40 PM »
Why do you think you are doing it wrong?

And what is the result that you got?
I don't know where I'm going wrong.

I don't ask where, I ask WHY do you think you are doing something wrong?

Quote
And then divided by 101.3 is 542.8 or 543

What for the division?
« Last Edit: November 24, 2012, 01:55:41 PM by Borek »
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Offline mudkip26

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Re: Coffee Cup Calorimetry?
« Reply #4 on: November 24, 2012, 02:02:06 PM »
Why do you think you are doing it wrong?

And what is the result that you got?
I don't know where I'm going wrong.

I don't ask where, I ask WHY do you think you are doing something wrong?

Quote
And then divided by 101.3 is 542.8 or 543

What for the division?
I think I might be using the wrong equation. I'm not really sure.

I'm dividing because I'm using the equation I need it in kJ not just J

Offline Borek

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Re: Coffee Cup Calorimetry?
« Reply #5 on: November 24, 2012, 02:32:09 PM »
I think I might be using the wrong equation. I'm not really sure.

OK. So it is possible you are right?

Quote
I'm dividing because I'm using the equation I need it in kJ not just J

What is the conversion factor between J and kJ (actually between any unit and kilounit)?
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline mudkip26

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Re: Coffee Cup Calorimetry?
« Reply #6 on: November 24, 2012, 03:52:57 PM »
I think I might be using the wrong equation. I'm not really sure.

OK. So it is possible you are right?

Quote
I'm dividing because I'm using the equation I need it in kJ not just J

What is the conversion factor between J and kJ (actually between any unit and kilounit)?
No because the online thing I am using tells me that I'm wrong.

It's 1000 J per 1 kJ correct?

Offline mudkip26

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Re: Coffee Cup Calorimetry?
« Reply #7 on: November 24, 2012, 04:47:37 PM »
I think I might be using the wrong equation. I'm not really sure.

OK. So it is possible you are right?

Quote
I'm dividing because I'm using the equation I need it in kJ not just J

What is the conversion factor between J and kJ (actually between any unit and kilounit)?
I solved it. Thank you.

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