December 23, 2024, 11:50:43 AM
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Topic: Chromic acid electrolysis  (Read 1549 times)

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Offline Rutherford

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Chromic acid electrolysis
« on: December 23, 2012, 05:31:56 AM »
How much time is needed when chromic acid is electrolysed (density of the current is 50A/dm2, 40% of the current is used), so that an area of 150cm2 is coated with a layer of Cr (thickness is 0.2mm)? Density of Cr is 7.1gcm-3.

The volume is V=150*0.02=3cm3, so the mass of Cr is m=7.1*3=21.3g, n=21.3/52=0.41mol
nFz=It therefore t=nFz/I
n is calculated, F=96500C/mol, z=6, I is calculated: I=50A/dm2*0.4*0.15dm2=3A
When I put all this I get that t≈22h, but the answer is 2.16h, much lower than I got. Where did I mistake?

Offline Borek

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Re: Chromic acid electrolysis
« Reply #1 on: December 23, 2012, 05:43:54 AM »
How many cm2 in dm2?
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Offline Rutherford

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Re: Chromic acid electrolysis
« Reply #2 on: December 23, 2012, 06:09:16 AM »
Yes ::), it is 1.5dm2. Then t=2.2h, so it is okay. Thanks for the correction.

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