This probably wouldn't work very well on a microscale, but as far as collecting the pollutants have you thought about a filter?. Pass all the combustion air through a filter. The smaller the pollutants your looking for the finer your filter should be. You should try to take all the combustion gas and pass it through a really small filter if your concentrations are to low.
As far as testing for the PAH on the food, I do not know.