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Topic: Oxidation of alcohols – substituting CH3COOH ?  (Read 1586 times)

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Offline organosurf

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Oxidation of alcohols – substituting CH3COOH ?
« on: February 07, 2013, 04:24:47 AM »
In the oxidation of alcohols using bleach, Sodium hypochlorite ( NaOCl ) and Glacial acetic acid
( CH3COOH ), does the glacial acetic acid act as a catalyst cum reaction participant and can it be substituted by other organic acids such as Citric acid or equivalent amount of mineral acid such as dil HCl ?

CH3COOH  +  H2O   ::equil::  CH3COO-  +  H3O+

NaOCl  +  CH3COOH   ::equil::  HOCl  +  CH3COO-Na+

NaOCl  +  HCl   ::equil::  HOCl  +  NaCl  ?

Cant find any answer to the above on the internet.


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