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Topic: Absolute configuration (Read 1929 times)
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gamerninja213
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Absolute configuration
«
on:
February 24, 2013, 09:25:36 PM »
Sorry. This might seem like a very stupid question, but when assigning absolute configuration for glyceraldehyde, why is it that CHO gets priority over HOCH2 ?
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camptzak
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Re: Absolute configuration
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Reply #1 on:
February 24, 2013, 10:18:10 PM »
The CHO carbon has two bonds to oxygen and one bond to hydrogen. The HOCH
2
carbon has two bonds to hydrogen and only one bond to oxygen. Since the CHO has more bonds to an element of higher atomic number, it has priority.
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Dan
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Re: Absolute configuration
«
Reply #2 on:
February 25, 2013, 03:11:27 AM »
See also:
http://en.wikipedia.org/wiki/Cahn%E2%80%93Ingold%E2%80%93Prelog_priority_rules
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Absolute configuration