From 20 mg of partially methylated disilane, Si
2H
6-x(CH
3)
x, 27.8 cm
3 of hydrogen are evolved during alkaline hydrolysis at 294 K and 97400 Pa. Calculate the degree of substitution x of the methylated disilane. Only Si-H and Si-Si bonds break.
I know to solve this, except one thing, the reaction. For example, the cleavage of the Si-H bond, I thought is:
Si-H+OH
- Si-OH+1/2H
2while it actually is:
Si-H+H
2O
Si-OH+H
2How could I known that it is the second reaction and not the first, when they said that it is an alkaline hydrolysis, so I expected OH
- ions to participate? Where is the logic behind this?