December 22, 2024, 08:14:48 AM
Forum Rules: Read This Before Posting


Topic: Wavelength Question  (Read 5726 times)

0 Members and 2 Guests are viewing this topic.

Offline alanjz

  • Regular Member
  • ***
  • Posts: 24
  • Mole Snacks: +1/-1
Wavelength Question
« on: March 24, 2013, 09:17:22 PM »
The question I'm struggling with is from the 2011 USNCO National Exam:

The first ionization energy of Na is 495.9 kJ*mol^-1. What is the longest wavelength of light that could remove an electron from a Na atom?
(A) 2.41x10^-7 m
(B) 2.41x10^-4 m
(C) 4.14 m
(D) 4.14x10^3 m

I tried:
E=hv=h(c/λ)
495.9x10^3=(6.626x10^-34)(2.998x10^8/λ)
λ=4.006x10^-31 m

I think this is the correct equation to use so could someone explain to me what I'm doing wrong?

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27885
  • Mole Snacks: +1815/-412
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Wavelength Question
« Reply #1 on: March 25, 2013, 05:03:48 AM »
Watch your units and it should become obvious.
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline alanjz

  • Regular Member
  • ***
  • Posts: 24
  • Mole Snacks: +1/-1
Re: Wavelength Question
« Reply #2 on: March 25, 2013, 09:21:25 AM »
495.9x10^3  =(6.626x10^-34)(2.998x10^8)/λ
We have J or kg*m2*s-2=(kg*m2*s-1)(m*s-1)/m so it looks like everything matches up.
I'm still not seeing it.

Offline Corribus

  • Chemist
  • Sr. Member
  • *
  • Posts: 3551
  • Mole Snacks: +546/-23
  • Gender: Male
  • A lover of spectroscopy and chocolate.
Re: Wavelength Question
« Reply #3 on: March 25, 2013, 09:35:13 AM »
You're forgetting to include one of the units in the piece of information provided.
What men are poets who can speak of Jupiter if he were like a man, but if he is an immense spinning sphere of methane and ammonia must be silent?  - Richard P. Feynman

Offline alanjz

  • Regular Member
  • ***
  • Posts: 24
  • Mole Snacks: +1/-1
Re: Wavelength Question
« Reply #4 on: March 25, 2013, 09:38:48 AM »
That helped me finally figure it out. I had to multiply by 6.02x10^23 since it said per mole. Thank you!

Sponsored Links