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Topic: 2-methylpentane from methylacetylene and nonane from 1-butene  (Read 1867 times)

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Offline katka1819

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2-methylpentane from methylacetylene and nonane from 1-butene
« on: September 17, 2013, 04:46:11 PM »
I have a little problem. How get 2-methylpentane from methylacetylene also nonane from 1-butene using only inorganic reagents. I don't have any idea how to start.
Thank for help.

Offline shalikadm

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Re: 2-methylpentane from methylacetylene and nonane from 1-butene
« Reply #1 on: September 17, 2013, 08:51:44 PM »
In the first problem,think like this,

You have 3 carbon atoms in the first molecule 6 in the second.
Now think of a way to connect those 2 carbon chains together.
Can you see that one of the chains marked red in the second molecule appears like that of a aldehyde/ketone. Now you should think that your conversion must have an intermediate aldehyde/ketone.
So you can do it in two different ways.

In the second problem,take it like this,

Here you have 4 left side and 9 right side. Now you have to add an extra carbon to the chain.
To add an extra carbon you can,
  • use CO2with grignard
  • use HCHO with grignard
But if you are give only to use 1- butene only as an organic compound , you have to use CO2 as it is considered as an inorganic compound.
You can do this conversion with the skill you get from the first problem.

Do it yourself and show what you have tried.

Offline antimatter101

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Re: 2-methylpentane from methylacetylene and nonane from 1-butene
« Reply #2 on: September 21, 2013, 02:21:00 AM »
Why not try oxymercuration? It gets you started straight away, and you get the answer quite quickly using oxymerc. (For first question only)

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