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Topic: Nernst Equation Help for Two Unknowns  (Read 1415 times)

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Offline offlinedoctor

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Nernst Equation Help for Two Unknowns
« on: October 04, 2013, 11:40:29 PM »
For the following question:
'Ni -> Ni2++2e- E°=-0.25
Co -> Co2++2e- E°=-0.28. If [Ni2+]=0.8M and [Co2+]=0.2M and, Ecell = 0.025, determine the concentration of Ni2+ at this point'.

What I did was:
1. Nernst Equation:
0.025 = 0.03 - 0.0591/2 x log (Co2+/Ni2+)
But I'm having trouble finding the concentration of Ni2+ at this point, when Ecell =0.025, because I've got two unknowns (Cu2+ aswell).
I was thinking of using the ICE table but wouldn't know if that would help in anyway.

Offline Borek

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Re: Nernst Equation Help for Two Unknowns
« Reply #1 on: October 05, 2013, 03:32:56 AM »
ICE table (or more generally - applying reaction stoichiometry) would be my approach as well.
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