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Topic: Methyl Benzoate/Benzyl Alcohol - Which More Polar?  (Read 8890 times)

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Offline dumakey1212

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Methyl Benzoate/Benzyl Alcohol - Which More Polar?
« on: March 06, 2014, 10:13:50 PM »
I'm doing column chromatography and need to predict which compound is more polar and thus which will travel more quickly and elute faster from the column. I know benzyl alcohol has the OH group, while methyl benzoate has the ester group with two Oxygen atoms present. Thanks for any help on this

Offline discodermolide

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Re: Methyl Benzoate/Benzyl Alcohol - Which More Polar?
« Reply #1 on: March 06, 2014, 10:30:06 PM »
On normal silica communes more polar compounds will travel more slowly. Because the are absorbed to the silica-gel.
So in your case which compound will be mere strongly adsorbed?

Consider the differences between the oxygen atoms.
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Offline Babcock_Hall

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Re: Methyl Benzoate/Benzyl Alcohol - Which More Polar?
« Reply #2 on: March 07, 2014, 12:44:45 PM »
It might help to think in terms of the common intermolecular forces.

Offline Archer

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Re: Methyl Benzoate/Benzyl Alcohol - Which More Polar?
« Reply #3 on: March 07, 2014, 02:04:41 PM »
On normal silica communes more polar compounds will travel more slowly. Because the are absorbed to the silica-gel.

Adsorbed  ;)

I appreciate this is a typo and not an error  ;D
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Offline discodermolide

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Re: Methyl Benzoate/Benzyl Alcohol - Which More Polar?
« Reply #4 on: March 07, 2014, 02:10:25 PM »
Sorry I was on the damm iPad with the spell checker, which is a pain in the backside.
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