December 22, 2024, 10:36:34 PM
Forum Rules: Read This Before Posting


Topic: Pd/C stereoselective?  (Read 6867 times)

0 Members and 1 Guest are viewing this topic.

Offline Nescafe

  • Full Member
  • ****
  • Posts: 346
  • Mole Snacks: +7/-11
Re: Pd/C stereoselective?
« Reply #15 on: April 26, 2014, 01:43:24 PM »
Sounds like good honest advice, appreciate the *delete me*

Offline Archer

  • Chemist
  • Sr. Member
  • *
  • Posts: 1001
  • Mole Snacks: +85/-20
  • Gender: Male
Re: Pd/C stereoselective?
« Reply #16 on: April 26, 2014, 01:59:30 PM »
I see a 60% of what the author's report and 40% of the other isomer. I was wondering if this is unusual since based on that paper it is almost a 100% conversion to one isomer. Might have to contact the authors directly.

I can't find any mention of yield in Scheme 3 of the paper.

If all else fails then your products should be separable with the right chromatography.


C[C@H](CCCC(C)C)[C@@H]1CC[C@@H]2[C@]1(CC[C@H]3[C@H]2CCC4[C@@]3(CC(C4)CCN)C)C



“ I love him. He's hops. He's barley. He's protein. He's a meal. ”

Denis Leary.

Sponsored Links