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Topic: Organic pathways that lead to longer Carbon chains?(like nitriles)  (Read 3226 times)

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Offline JD46

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Hi!

So I'm compiling all the pathways and just adding notes on the tricky ones, I remember Nitriles doing this because the CN- ion has carbon, but are there any other pathways I'm leaving out?

Offline kriggy

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Re: Organic pathways that lead to longer Carbon chains?(like nitriles)
« Reply #1 on: May 15, 2014, 02:42:45 AM »
You mean like reactions which longers the carbon chains?
try this
http://en.wikipedia.org/wiki/Coupling_reaction

Offline JD46

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Re: Organic pathways that lead to longer Carbon chains?(like nitriles)
« Reply #2 on: May 15, 2014, 03:22:14 AM »
Hi! I don't think those are it, they don't have the nitrile one and seem really advanced, I'm just in need of 12th type reactions :)

Offline Dan

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Re: Organic pathways that lead to longer Carbon chains?(like nitriles)
« Reply #3 on: May 15, 2014, 03:28:53 AM »
This is a very general question because any C-C bond forming reaction could potentially result in a longer carbon chain - there are an enormous number of them.

Maybe what you're interested in is homologation reactions?
My research: Google Scholar and Researchgate

Offline JD46

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Re: Organic pathways that lead to longer Carbon chains?(like nitriles)
« Reply #4 on: May 15, 2014, 03:39:15 AM »
I was hoping the example would provide a clue as to which ones I'm dealing with, sorry if it's still vague though.

Offline kriggy

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Re: Organic pathways that lead to longer Carbon chains?(like nitriles)
« Reply #5 on: May 15, 2014, 04:48:47 AM »
Hi! I don't think those are it, they don't have the nitrile one and seem really advanced, I'm just in need of 12th type reactions :)
Oh I see. Ok maybe this one
http://en.wikipedia.org/wiki/Kiliani%E2%80%93Fischer_synthesis
It longers sacharide chain by 1 carbon
Or
http://en.wikipedia.org/wiki/Grignard_reaction#Reactions_with_other_electrophiles
Reacting grignard reagent with nitrile creates ketone, but I think the 1st one suits your question better

Offline JD46

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Re: Organic pathways that lead to longer Carbon chains?(like nitriles)
« Reply #6 on: May 15, 2014, 06:09:00 AM »
Thanks for trying but I'll just call up another student and check, I can now see why my question was impossible. I'm sorry for the inconvenience!

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