[Ingeniosuccinimide]

I have an assignment to do, where one of the tasks is to mark with arrows all possible interactions and couplings that could theoretically/practically be seen in the NOESY, TOCSY and ROESY spectra of the molecule in the attachment (afterwards we are supposed to do the experiments and analyze spectra).

Could anyone help me with the given molecule or even better explain or reccommend some lecture on how to theoretically propose possible interactions between nuclei just by observing the structure (I'm asking this because I suppose interactions can't simply happen everywhere, there should be some rule or explanation)?

[discodermolide]

Here is a basic intro.
http://en.wikipedia.org/wiki/Nuclear_Overhauser_effect
perhaps you can deepen your knowledge by using the links in that article.