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Topic: Finding Colour of precipitate  (Read 2489 times)

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Offline crusader643

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Finding Colour of precipitate
« on: June 29, 2014, 04:46:32 AM »
Hey,

I was wondering if there is anyway to determine the colour of a precipitate without actually seeing it?
Such as when KI + Pb(NO3)2  :rarrow: PbI2
When you mix the two colourless solutions solutions together you get yellow precipitate, is it possible to determine what colour the PbI2 is without seeing it?

Thanks

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Re: Finding Colour of precipitate
« Reply #1 on: June 29, 2014, 07:00:26 AM »
is it possible to determine what colour the PbI2 is without seeing it?

In theory - yes, it should be doable to calculate, that's what quantum mechanics is about.

In reality it is not that easy.

Besides, color of PbI2 depends on the temperature.
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Offline Corribus

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Re: Finding Colour of precipitate
« Reply #2 on: June 29, 2014, 12:44:26 PM »
Measure absorption spectrum with your eyes closed, see what wavelengths are absorbed, extrapolate to color.

Although bear in mind that perceived color depends on environmental factors (ambient light, physiology of the eye, etc.) in addition to molecular properties.
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Offline MrTeo

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Re: Finding Colour of precipitate
« Reply #3 on: June 29, 2014, 02:55:44 PM »
In reality it is not that easy.

Right. Moreover, considering that we're talking about a solid, different crystalline forms could give different colours. This is exactly what happens when you heat HgI2. So it also depends on the crystallization (or precipitation, which is microcrystallization) conditions.
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