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Topic: desulfurization of thioacetals  (Read 2892 times)

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Offline davidenarb

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desulfurization of thioacetals
« on: August 15, 2014, 09:39:33 AM »
hi all,

I know that the first reaction is correct. my concern is pointed to the second reaction. is it correct??

Offline rwiew

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Re: desulfurization of thioacetals
« Reply #1 on: August 15, 2014, 09:47:01 AM »
The second one is wrong - you've added 2 extra carbons is the biggest problem, where do they come from? Based on the first reaction, what would be an expected product in the second one?

Offline davidenarb

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Re: desulfurization of thioacetals
« Reply #2 on: August 15, 2014, 09:52:05 AM »
The second one is wrong - you've added 2 extra carbons is the biggest problem, where do they come from? Based on the first reaction, what would be an expected product in the second one?

is propane expected for the second reaction?

Offline Babcock_Hall

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Re: desulfurization of thioacetals
« Reply #3 on: August 15, 2014, 10:46:38 AM »
In your first example, the C-S bond was replaced with what kind of bond?  Use this reaction as your model.

Offline davidenarb

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Re: desulfurization of thioacetals
« Reply #4 on: August 15, 2014, 11:25:25 AM »
In your first example, the C-S bond was replaced with what kind of bond?  Use this reaction as your model.

Soory i mean will we have pentane??

Offline Babcock_Hall

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Re: desulfurization of thioacetals
« Reply #5 on: August 15, 2014, 11:43:35 AM »
Yes.

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