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Topic: IUPAC name of tree-like compound  (Read 3787 times)

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Offline Shadow

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IUPAC name of tree-like compound
« on: August 26, 2014, 07:37:14 AM »
What is the iupac name of the attached compound?
Can it be synthesized with all that steric hindrance?

Offline discodermolide

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Re: IUPAC name of tree-like compound
« Reply #1 on: August 26, 2014, 08:56:44 AM »
Find the longest carbon chain.
It probably can be made, it's a question of experimentation.
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Offline zsinger

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Re: IUPAC name of tree-like compound
« Reply #2 on: August 26, 2014, 06:30:23 PM »
A big heptane!  Very substituted…..would run into many problems, as you said, bc of sterics.
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Offline Enthalpy

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Re: IUPAC name of tree-like compound
« Reply #3 on: August 27, 2014, 10:13:20 AM »
Much more cluttered hydrocarbons are synthesized, check the online Pdf:
Consequences of strain for the structure of aliphatic molecules
by Christoph Rüchardt and Hans-Dieter Backhaus
they synthesized through usual means like Wurz or by dimerization of azoalkanes or through hydrogen abstraction...

Offline adonwen

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Re: IUPAC name of tree-like compound
« Reply #4 on: September 05, 2014, 12:01:37 AM »
Wouldn't it be 2,2,3,3,5,5,6,6-octamethyl-4-(1,1,2,2-tetramethylpropyl)heptane?

Offline discodermolide

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Re: IUPAC name of tree-like compound
« Reply #5 on: September 05, 2014, 01:32:23 AM »
How about 2,2,3,3,5,5,6,6-octamethyl-4-(2,3,3-trimethylbutan-2-yl)heptane?.
CC(C)(C(C)(C)C)C(C(C)(C(C)(C)C)C)C(C)(C(C)(C)C)C
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Offline Alpha Carbon

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Re: IUPAC name of tree-like compound
« Reply #6 on: September 08, 2014, 07:36:20 PM »
2,2,3,3,5,5,6,6-octamethyl-4-(1,1,2,2-tetramethylpropyl)heptane is the correct name

Offline discodermolide

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Re: IUPAC name of tree-like compound
« Reply #7 on: September 08, 2014, 11:10:23 PM »
2,2,3,3,5,5,6,6-octamethyl-4-(1,1,2,2-tetramethylpropyl)heptane is the correct name


And you know this, how?
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Offline curiouscat

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Re: IUPAC name of tree-like compound
« Reply #8 on: September 09, 2014, 02:38:45 AM »
CC(C)(C)C(C)(C)C(C(C)(C)C(C)(C)C)C(C)(C)C(C)(C)C

My robot slave says  2,2,3,3,5,5,6,6-octamethyl-4-(2,3,3-trimethylbutan-2-yl)heptane

Offline discodermolide

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Re: IUPAC name of tree-like compound
« Reply #9 on: September 09, 2014, 02:44:46 AM »
You must have the same robot as me  ::)
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Offline curiouscat

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Re: IUPAC name of tree-like compound
« Reply #10 on: September 09, 2014, 02:51:13 AM »
Trying to trick my slave now....

C(C(C)(C)C(C)(C)C)(C(C)(C)C(C)(C)C)(C(C)(C)C(C)(C)C)

Dang. It's too smart for me. No matter how I write SMILES robot gives same canonical name.


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