December 26, 2024, 11:15:36 PM
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Topic: Sterioisomerism  (Read 2507 times)

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Offline Pico

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Sterioisomerism
« on: October 14, 2014, 09:04:28 PM »
In the complex [Co(en)2(H2O)2]Cl3, how could you experimentally determine whether the Cl ions are not bound directly to the central Co(III) atom?

Also if the complex was treated with oxalate, two complexes are isolated [Co(en)2(ox)(H2O)]Cl and [Co(en)2(ox)]Cl. Would there be a preference for (ox) being monodentate or bidentate? Why are both formed? Would there be two diastereoisomers of [Co(en)2(ox)(H2O)]Cl and two enantiomers for [Co(en)2(ox)]Cl?

Thanks in advance

Offline Hunter2

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Re: Sterioisomerism
« Reply #1 on: October 15, 2014, 12:46:27 AM »
Hint: how to detect chloride?

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