November 21, 2024, 11:32:35 AM
Forum Rules: Read This Before Posting


Topic: extraction of esters in organometallics  (Read 5302 times)

0 Members and 2 Guests are viewing this topic.

kumarentran

  • Guest
extraction of esters in organometallics
« on: July 27, 2004, 04:07:46 AM »
i have synthesised an organometallic compound.(blue powder)
its copper(ii) benzoate which is a dimer compound with 4  4-halobenzoate ligands.
i estherified it by dissolving it in ethanol first and then adding 6M HCl (about 3ml).
the colour changed from tranparent to yellowish green solution with a slight smell of ester( sweet smell).
now i have to characterise i.
but i find it hard to extract the ester from the mixture.
i have tried extraction with choloform as i lack methylene chloride.
the choloform didnt quite seem to seperate the ester from the acid and ethanol mixture.
i also tried levelled distillation but the product is very less and th ester smell is very low as the sharp and strong acid smell intervenes.
can u describe me a way to retrieve the neutral ester without the acid

Offline movies

  • Organic Minion
  • Retired Staff
  • Sr. Member
  • *
  • Posts: 1973
  • Mole Snacks: +222/-21
  • Gender: Male
  • Better living through chemistry!
Re:extraction of esters in organometallics
« Reply #1 on: July 27, 2004, 12:33:45 PM »
How about extracting with ether or ethyl acetate from a basic aqueous solution?  That should deprotonate the acid and force it to remain in the aqueous layer.

Sponsored Links