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Topic: TPAP,NMMO : mecanism  (Read 4945 times)

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Offline faust

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TPAP,NMMO : mecanism
« on: April 07, 2006, 01:28:00 PM »
Hello,

Another question of mechanism, do you have an idea of the mechanism of a primary alcohol oxyded to an acid via the catalytic couple TPAP/NMMO
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Offline movies

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Re: TPAP,NMMO : mecanism
« Reply #1 on: April 12, 2006, 02:35:52 PM »
The mechanism of this reaction isn't know.  You could draw a mechanism similar to the oxidation of alcohols by chromium species, but some research on the TPAP system has suggested that the oxidation may occur through a radical process.
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