Think of the quantum numbers and how they all relate to each other. And how the periodic table is built around these quantum numbers.
To describe an orbital you need three quantum numbers:
n (principle),
l (angular momentum), and
ml (magnetic). To describe the electrons in those orbitals you need a fourth quantum number:
ms (spin).
- The principle number n can take on values between 1 and ∞.
- The angular momentum number l can take on values between 0 and [itex]n-1[/itex] (and this is the quantum number that represents the shells s, p, d, f...).
- The magnetic number ml can take on values between [itex]-l...0...l[/itex].
- The spin quantum number ms can take on values of [itex]-\frac{1}{2}[/itex] and [itex]+\frac{1}{2}[/itex].
Each element has a unique electron configuration described by the four quantum numbers. And you can predict the electron configuration by following the rules of the Aufbau principle.
To make it easier on yourself, maybe first try some easy examples that are within the known periodic table. What would be the electron configuration of the 5th element? The 10th? What about the 100th? How do these electron configurations relate to groups?
For the 5th element we need 5 electrons, so we have:
- [itex]n=1,l=0,m_l=0,m_s=-\frac{1}{2}[/itex]
- [itex]n=1,l=0,m_l=0,m_s=+\frac{1}{2}[/itex]
- [itex]n=2,l=0,m_l=0,m_s=-\frac{1}{2}[/itex]
- [itex]n=2,l=0,m_l=0,m_s=+\frac{1}{2}[/itex]
- [itex]n=2,l=1,m_l=-1,m_s=-\frac{1}{2}[/itex]
Where was the last (5th) electron added in the example above? Which group would it be put in?
You could continue this exercise for the 170th electron, which would be tedious. Could you think of a shortcut, though? Maybe try to think of how many electrons there can possibly be for a given primary quantum number, [itex]n[/itex].