You can do many experiments, also the more dangerous ones, but you have to follow a few rules:
1) Study the properties of the chemicals and the possible products. Take time for this.
2) Think about what
might go wrong and think about what you need to do in that case. If this means that you need to do some special preparation (e.g. make an antidote) then do that.
3) Take safety precautions (e.g. good ventilation, or even a fumehood, or with lack of other options, do the experiment outside on a windy day).
4)
Use small quantities. This is very important. If you use less than say 100 mg of reagents and you let the reaction run at a distance of at least a meter or so, outside, then even with the most energetic materials nothing serious can happen.
Look at my website. A lot of nice experiments, some quite dangerous, but I could perform them all, and I'm still here to write this post
. All these experiments were done at home, not in a special lab.
http://woelen.scheikunde.net/science/chem/exps/index3.html