January 15, 2025, 04:08:17 PM
Forum Rules: Read This Before Posting


« previous next »
Pages: [1]   Go Down

Topic: Mechanism for this Scheme  (Read 1779 times)

0 Members and 3 Guests are viewing this topic.

Offline nayeee1m

  • Regular Member
  • ***
  • Posts: 14
  • Mole Snacks: +3/-2
  • Gender: Male
Mechanism for this Scheme
« on: April 01, 2016, 03:15:04 AM »
I am trying to figure out this mechanism . Looks like easy but really hard for me. Please help me out.
Specially from
9 to 8-Me
8-H to 7-me
10 to 6-me
6-Me to 5-me
Please help me out 
Refeence: http://pubs.acs.org/doi/pdfplus/10.1021/acs.orglett.6b00404
Logged
nayem

Offline orgopete

  • Chemist
  • Sr. Member
  • *
  • Posts: 2636
  • Mole Snacks: +213/-71
    • Curved Arrow Press
Re: Mechanism for this Scheme
« Reply #1 on: April 02, 2016, 09:20:29 AM »
My hints:
Quote from: nayeee1m on April 01, 2016, 03:15:04 AM
9 to 8-Me
Alkylation, Claisen, hydrolysis, (high temp) decarboxylation.
Quote
8-H to 7-me
10 to 6-me
Friedel-Crafts
 
Quote
6-Me to 5-me
Expoxidation, hydrolysis, ketalization. I'm hoping this is enough. Can you show us the reactions?
Logged
Author of a multi-tiered example based workbook for learning organic chemistry mechanisms.
Pages: [1]   Go Up
« previous next »
Sponsored Links