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Topic: P31 NMR of PPh2F3  (Read 2103 times)

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Offline maverick1996

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P31 NMR of PPh2F3
« on: April 25, 2016, 03:37:24 PM »
Hey!

So I understand that the Phenyl groups have to be Equatorial leaving three Flourines, one equatorial and two axial (so two phosphorus environments). So why does this lead to 2 triplets? I would of thought that it would be q doublet and triplet

Can somebody please explain this?

Thanks
« Last Edit: April 25, 2016, 03:49:28 PM by maverick1996 »

Offline mjc123

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Re: P31 NMR of PPh2F3
« Reply #1 on: April 25, 2016, 04:27:56 PM »
Why would you get a doublet and triplet? There is only one P, so only one signal. Both splittings operate on the same signal, so you get a doublet of triplets (assuming the equatorial splitting is greater than the axial).

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