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cyclopantane-1,2-diol
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Topic: cyclopantane-1,2-diol (Read 2243 times)
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anandjha
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cyclopantane-1,2-diol
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on:
May 14, 2016, 01:53:55 AM »
Hello Everyone
Can someone tell me if there are methods for chemically distinguishing cis-cyclopantane-1,2-diol and trans-cyclopantane-1,2-diol.
Thanks
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Dan
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Re: cyclopantane-1,2-diol
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Reply #1 on:
May 14, 2016, 04:29:29 AM »
What reactions of vicinal diols do you know?
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OCSaviour
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Re: cyclopantane-1,2-diol
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Reply #2 on:
May 14, 2016, 10:39:41 AM »
Adding to Dan's hint, I would like to give an extra hint. One of these reactions of glycols involves the formation of a ring.
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anandjha
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Re: cyclopantane-1,2-diol
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Reply #3 on:
May 14, 2016, 11:57:55 AM »
thanks
I think I got it
by protecting cis one with acetone for formation of Acetonides
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Dan
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Re: cyclopantane-1,2-diol
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Reply #4 on:
May 14, 2016, 02:10:15 PM »
Acetonide protection would certainly work, yes.
The other reaction that springs to mind is oxidative cleavage with periodate.
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Babcock_Hall
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Re: cyclopantane-1,2-diol
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Reply #5 on:
May 14, 2016, 05:09:31 PM »
It might be worth looking into borates, but I am not certain (just thinking out loud).
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cyclopantane-1,2-diol