December 21, 2024, 10:14:07 AM
Forum Rules: Read This Before Posting


Topic: Transition metals  (Read 2500 times)

0 Members and 1 Guest are viewing this topic.

Offline Heisenberg97

  • Regular Member
  • ***
  • Posts: 12
  • Mole Snacks: +0/-0
Transition metals
« on: May 15, 2016, 08:40:05 AM »
1) What actually is a weak field/strong field ligand and how does it lead to high and low spin respectively?

2) Why don't transition metal complexes exist when the transition metal has a high oxidation state? (e.g. FeO4 with Fe in the +8 oxidation state)

Offline AWK

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 7976
  • Mole Snacks: +555/-93
  • Gender: Male
Re: Transition metals
« Reply #1 on: May 15, 2016, 10:08:19 AM »
There is no such compound as FeO4. FeO42- salts exist. relatively stable OsO4 is known.
For 1)
read wikipedia and a few times your textbook.
https://www.wikiwand.com/en/Ligand_field_theory
http://chemwiki.ucdavis.edu/Core/Inorganic_Chemistry/Crystal_Field_Theory/High_Spin_and_Low_Spin_Complexes
AWK

Sponsored Links