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Topic: sodium naphthalenide as reducing agent,is it reacts with methanol?  (Read 1882 times)

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Offline santi prasad rath

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sodium naphthalenide as reducing agent,is it reacts with methanol?
« on: June 27, 2016, 05:32:00 AM »
I have a N=N ligand which get reduced and hydrogenated (NH-NH) by Zn dust in presence of methanol.But Zn has a bad effect, sometimes oxidized form of Zn(Zn2+) replaces the metal complex.so can I use sodium naphthalenide quantitatively as reducing agent,is it reacts with methanol ?
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Offline Hunter2

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Re: sodium naphthalenide as reducing agent,is it reacts with methanol?
« Reply #1 on: July 04, 2016, 08:28:57 AM »
Sodium naphthalenide is not stable in protic solvents like alcohols. You need Ether or better Terahydrofurane.
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