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Topic: pKa value of dicarbonyl compounds  (Read 2351 times)

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Offline Richard Jeong

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pKa value of dicarbonyl compounds
« on: September 23, 2016, 06:13:07 AM »
As we see in the pKa value table in organic chemistry, the pKa value of α-hydrogen for-

acetylacetone(diketone): 9
ethyl acetoacetate(β-keto ester): 11
diethyl malonate(diester): 13

What causes this difference? Is there any special things for anionic ester resonance?
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