Hi, I have a doubt about the ligand CO in organometallic compounds
Please hel me,is important!!!
PREMISE:
I know that the lewis structure of CO is:
|C≡O| <----> |C=O||
Now if I have an organometallic compound like M(CO)
4 :
---CO
-----|
CO-M-OC
-----|
---CO
I can say that each CO ligand "give" a lone pair (the lone pair of "C") to the metallic centre... a "kind" of dative bond
MY DOUBT: is when I have a BRIDGING CO ligand : a CO "linked"to TWO metallic "atoms" , Me.
-------CO
------/---\
----Me---Me
I don't understand the electronic situation of the CO in this compound....
a Usually (in this type of "bridge compounds" )are the two bond with (2) Me two dative bond ??
How can CO donate two lone pair?? ....C has only 1 lone pair.
OR
b) is a three-center two-electron bond?? Where C in CO donates its lone pair at the two metallic centers??
Thanks !!